135722-63-3

Basic information

• Product Name: [1,1'-Biphenyl]-4-amine, 4'-methoxy-N,N-diphenyl-
• CAS NO: 135722-63-3
• Molecular Formula: C25H21NO
• Molecular Weight: 351.448
• Mol File: 135722-63-3.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: [1,1'-Biphenyl]-4-amine, 4'-methoxy-N,N-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-Biphenyl]-4-amine, 4'-methoxy-N,N-diphenyl-(135722-63-3)
• EPA Substance Registry System: [1,1'-Biphenyl]-4-amine, 4'-methoxy-N,N-diphenyl-(135722-63-3)

Safety Data

• Hazardous Substances Data: 135722-63-3(Hazardous Substances Data)

Upstream product

• 122-39-4 diphenylamine 
• 696-62-8 para-iodoanisole 
• 201802-67-7 4-(diphenylamino)phenyl boronic acid 
• 15183-74-1 1-methoxy-4-((trifluoromethyl)sulfonyl)benzene 
• 21502-70-5 tris(p-anisyl)antimony 
• 36809-26-4 4-N,N-diphenylamino-1-bromobenzene 
• 5720-07-0 4-methoxyphenylboronic acid 
• 603-34-9 N,N-diphenylaminobenzene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 416857-85-7 10-hydroxy-10-methyl-2,2-diphenyl-2H-pyrano[6,5-b]fluorene 

Downstream Products

• 933066-97-8 [4-(2,2-diphenyl-2H-chromen-6-yl)-phenyl]-diphenyl-amine 
• 159892-55-4 4′?(N,N?diphenylamino)?[1,1′?biphenyl]?4?ol 

Relevant articles and documents

Pd Nanoparticles Embedded Into MOF-808: Synthesis, Structural Characteristics, and Catalyst Properties for the Suzuki–Miyaura Coupling Reaction

Abstract: A heterogeneous single-site catalyst Pd@MOF-808 was successfully synthesized by water-based, green synthesis procedure. The catalytic experiments exhibited the Pd@MOF-808 promoted efficiently the Suzuki–Miyaura coupling reaction without the assistance of organic phosphine ligands at atmospheric pressure conditions. The catalyst also could be applied in the gram-scale synthesis of industrially anti-inflanmatory analgestic Fenbufen. Graphic Abstract: [Figure not available: see fulltext.]

Suzuki–Miyaura Coupling of (Hetero)Aryl Sulfones: Complementary Reactivity Enables Iterative Polyaryl Synthesis

Ideal organic syntheses involve the rapid construction of C?C bonds, with minimal use of functional group interconversions. The Suzuki–Miyaura cross-coupling (SMC) is a powerful way to form biaryl linkages, but the relatively similar reactivity of electrophilic partners makes iterative syntheses involving more than two sequential coupling events difficult to achieve without additional manipulations. Here we introduce (hetero)aryl sulfones as electrophilic coupling partners for the SMC reaction, which display an intermediate reactivity between those of typical aryl (pseudo)halides and nitroarenes. The new complementary reactivity allows for rapid sequential cross-coupling of arenes bearing chloride, sulfone and nitro leaving groups, affording non-symmetric ter- and quateraryls in only 2 or 3 steps, respectively. The SMC reactivity of (hetero)aryl sulfones is demonstrated in over 30 examples. Mechanistic experiments and DFT calculations are consistent with oxidative addition into the sulfone C?S bond as the turnover-limiting step. The further development of electrophilic cross-coupling partners with complementary reactivity may open new possibilities for divergent iterative synthesis starting from small pools of polyfunctionalized arenes.

Carbonyl compound with diphenylbenzidine as conjugate main body structure as well as preparation method and application of carbonyl compound

The invention relates to the technical field of new material organic chemicals, in particular to a carbonyl group-containing novel photoinitiator with diphenylbenzidine as a conjugate main body structure, shown as a formula (I), a chemical preparation process technology of the carbonyl group-containing novel photoinitiator, use of the carbonyl group-containing novel photoinitiator as a radiation curing photoinitiator, a radiation curing formula product of the carbonyl group-containing novel photoinitiator and particularly application use of the carbonyl group-containing novel photoinitiator invarious places of photocureable coatings, printing ink or the like. The formula (I) is described in the following description.