135743-80-5Relevant articles and documents
Efficient conversion of aucubin into 6-epi-aucubin
Cachet, Xavier,Deguin, Brigitte,Koch, Michel,Makhlouf, Kader,Tillequin, Francois
, p. 400 - 402 (1999)
Selective deprotection of peracetylaucubin (3) by use of KCN led to 6- O-acetylaucubin (4), which was readily converted into 2',3',4',6',10-penta- O-benzoylaucubin (7). Configuration inversion performed on 7, using a modified Mitsunobu reaction, followed by deprotection, afforded 6-epi- aucubin (2).