135950-88-8Relevant articles and documents
The synthesis and evaluation of new α-hydrogen nitroxides for 'living' free radical polymerization
Braslau, Rebecca,O'Bryan, Greg,Nilsen, Aaron,Henise, Jeff,Thongpaisanwong, Thanchanok,Murphy, Erin,Mueller, Laura,Ruehl, Jean
, p. 1496 - 1506 (2007/10/03)
Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic α-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO. Georg Thieme Verlag Stuttgart.