1359762-09-6

Basic information

• Product Name: [Ir(2-(2-naphthyl)-4,6-dimethyl-pyrimidine-H)(PPh₃)2Cl₂]
• CAS NO: 1359762-09-6
• Molecular Weight: 1021
• Mol File: 1359762-09-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ir(2-(2-naphthyl)-4,6-dimethyl-pyrimidine-H)(PPh₃)2Cl₂](CAS DataBase Reference)
• NIST Chemistry Reference: [Ir(2-(2-naphthyl)-4,6-dimethyl-pyrimidine-H)(PPh₃)2Cl₂](1359762-09-6)
• EPA Substance Registry System: [Ir(2-(2-naphthyl)-4,6-dimethyl-pyrimidine-H)(PPh₃)2Cl₂](1359762-09-6)

Safety Data

• Hazardous Substances Data: 1359762-09-6(Hazardous Substances Data)

Upstream product

• 10025-83-9 iridium (III) chloride 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Triphenylphosphine-cyclometallated iridium(III) pyrimidine complexes: Synthesis, crystal structures and application in α-alkylation of ketones with alcohols

Two triphenylphosphine (PPh3)-cyclometallated iridium(III) pyrimidine complexes Ir(NDMP)2PPh3Cl 1 and Ir(NDMP)(PPh3)2Cl2 2 (NDMP = 2-(2-naphthyl)-4,6- dimethyl-pyrimidine) were synthesized and characterized by NMR, IR, ESI-MS, and elemental analysis. Additionally, their detailed structures have been determined by X-ray single-crystal diffraction. The complex 1 was a PPh3-biscyclometalated Ir(III) complex, while 2 was a PPh 3-monocyclometalated Ir(III) complex. These complexes were found to be efficient catalysts for α-alkylation of ketones with alcohols.