136054-69-8

Basic information

• Product Name: trans-6-phenyl-4-hexen-1-ol
• Synonyms: trans-6-phenyl-4-hexen-1-ol
• CAS NO: 136054-69-8
• Molecular Weight: 176.258
• Mol File: 136054-69-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: trans-6-phenyl-4-hexen-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: trans-6-phenyl-4-hexen-1-ol(136054-69-8)
• EPA Substance Registry System: trans-6-phenyl-4-hexen-1-ol(136054-69-8)

Safety Data

• Hazardous Substances Data: 136054-69-8(Hazardous Substances Data)

Upstream product

• 300-57-2 allylbenzene 
• 821-09-0 n-Pent-4-enyl alcohol 
• 189080-22-6 methyl trans-6-phenyl-4-hexenoate 
• 41049-27-8 (E)-6-Phenyl-hex-4-enal 
• 5631-95-8 2,3-dichlorotetrahydro-2H-pyran 
• 100-44-7 benzyl chloride 

Downstream Products

• 1032592-10-1 (R)-2-((R)-1-iodo-2-phenylethyl)tetrahydrofuran 
• 1361202-86-9 C₁₇H₂₇NOS 
• 41049-27-8 cis-6-phenylhex-4-enal 
• 15382-76-0 1-Phenyl-6-<4-amino-2-methoxy-phenoxy>-hexan 
• 102010-90-2 1-Phenyl-6-(4-nitro-2-methoxy-phenoxy)-hexan 
• 27976-27-8 (6-bromohexyl)benzene 
• 2430-16-2 6-phenyl-1-hexanol 

Relevant articles and documents

Pyrrolidines and Piperidines by Ligand-Enabled Aza-Heck Cyclizations and Cascades of N-(Pentafluorobenzoyloxy)carbamates

Ligand-enabled aza-Heck cyclizations and cascades of N-(pentafluorobenzoyloxy)carbamates are described. These studies encompass the first examples of efficient non-biased 6-exo aza-Heck cyclizations. The methodology provides direct and flexible access to carbamate protected pyrrolidines and piperidines.

Diverse N-Heterocyclic Ring Systems via Aza-Heck Cyclizations of N-(Pentafluorobenzoyloxy)sulfonamides

Aza-Heck cyclizations initiated by oxidative addition of Pd0-catalysts into the N?O bond of N-(pentafluoro-benzoyloxy)sulfonamides are described. These studies, which encompass only the second class of aza-Heck reaction developed to date, provide direct access to diverse N-heterocyclic ring systems.

A pH Study on the Chiral Ketone Catalyzed Asymmetric Epoxidation of Hydroxyalkenes

A detailed study shows that the chiral ketone catalyzed asymmetric epoxidations of hydroxyalkenes are highly pH dependent. The lower enantioselectivity obtained at low pH is attributed to the substantial contribution of the direct epoxidation by Oxone. At high pH the epoxidation mediated by chiral ketone out-competes the racemic epoxidation, leading to higher enantioselectivity. The effective substrates include allylic alcohol, homoallylic alcohol, and bishomoallylic alcohol. In most cases, over 90% ee was obtained.