1361015-92-0Relevant articles and documents
Molybdenum tin-containing π-complexes (R3SnCH=CH 2)Mo(N-2,6-Pr2i-C6H 3)(OCMe2CF3)2. Synthesis and catalytic properties
Barinova,Bochkarev,Kurskii,Abakumov
, p. 17 - 22 (2012/06/04)
The tin-containing molybdenum π-complexes (R3SnCH=CH 2)Mo(N-2,6-Pr2iC6H 3)(OCMe2CF3)2 (R = Me, Et, Ph) were synthesized by reaction of PhMe2CCH=Mo(N-2,6-Pr2 iC6H3)(OCMe2CF3) 2 with organotin vinyl reagents R3SnCH=CH2. The structure of compounds I-III was determined by NMR spectroscopy. Complexes I-III are active initiators of the norbornene metathesis polymerization.