136132-58-6

Basic information

• Product Name: 3-[tert-butyl(dimethyl)silyl]-2-benzothiophene-1-carbaldehyde
• Synonyms: 3-[tert-butyl(dimethyl)silyl]-2-benzothiophene-1-carbaldehyde
• CAS NO: 136132-58-6
• Molecular Formula: C15H20OSSi
• Molecular Weight: 276.4692
• Mol File: 136132-58-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-[tert-butyl(dimethyl)silyl]-2-benzothiophene-1-carbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[tert-butyl(dimethyl)silyl]-2-benzothiophene-1-carbaldehyde(136132-58-6)
• EPA Substance Registry System: 3-[tert-butyl(dimethyl)silyl]-2-benzothiophene-1-carbaldehyde(136132-58-6)

Safety Data

• Hazardous Substances Data: 136132-58-6(Hazardous Substances Data)

Upstream product

• 136132-54-2 1,3-dichloro-2-benzothiophene 
• 13169-42-1 1,1,3,3-tetrachlorothiophthalan 
• 5698-59-9 benzo[c]thiophene-1,3-dione 
• 136132-57-5 1,3-bis(tert-butyldimethylsilyl)isothianaphthene 
• 68-12-2 N,N-dimethyl-formamide 

Relevant articles and documents

A New Route to 1,3-Disubstituted Benzothiophenes

A facile synthesis of 1,3-dichlorobenzothiophene 3 is described.Lithium-chlorine exchange of 3, followed by reaction with various electrophiles, provides a route to 1-acyl-3-chlorobenzothiophenes, as well as to the very stable 1,3-bis(tert-butyldimethylsilyl)benzothiophene (9).Compound 9 unddergoes silyl replacement reactions with acylating agents, as well as an unusuak oxidative desilylation by I2 or TiCl4, to give the capped disilylated dimer, trimer, and tetramer (16,17, and 18) of benzothiophene.