13616-71-2Relevant articles and documents
Metal-assisted fragmentation of N-aryl- and -alkyl-N-trimethylsilylaminosulfur chlorides and N-aryl- and -alkyl-aminosulfur chlorides in the presence of conjugated dienes: Synthesis and reactivity of 2-substituted-3,6-dihydro-1,2-thiazines
Bryce, Martin R.,Chesney, Antony,McKelvey, Graham N.,Batsanov, Andrei S.,Howard, Judith A. K.,Anderson, Martin
, p. 1825 - 1831 (2007/10/03)
N-Alkyl- and -aryl-N-trimethylsilylaminosulfur chlorides 2 and N-aryl- and -alkyl-aminosulfur chlorides 8 fragment in the presence of silver ions and a conjugated diene to yield 2-substituted-3,6-dihydro-1,2-thiarines 6 as the major products, possibly via
Diels-Alder and Ene Reactions of New Transient Thionitrosoarenes (Ar-N=S) and Thionitrosoheteroarenes (Het-N=S) Generated from N-(Arylaminosulfanyl)- and N-(Heteroarylaminosulfanyl)-phthalimides: Synthesis of Cyclic and Acyclic Sulfenamides
Bryce, Martin R.,Heaton, Julie N.,Taylor, Paul C.,Anderson, Martin
, p. 1935 - 1944 (2007/10/02)
A series of new N-(arylaminosulfanyl)- and N-(heteroarylaminosulfanyl)-phthalimide derivatives 3i-m and 3o-r, has been prepared by reaction of chlorosulfanylphthalimide with the trimethylsilyl derivative of the appropriate arylamine or heteroarylamine.On
Efficient Generation of Thionitrosoarenes (ArN=S) by Fragmentation of N-(Arylaminothio)phthalimides
Bryce, Martin R.,Taylor, Paul C.
, p. 950 - 951 (2007/10/02)
Base-induced fragmentation of a series of N-(arylaminothio)phyhalimides (3) provides an efficient route to transient thionitrosoarenes (2); compounds (2) have been trapped as Diels-Alder cycloadducts with butadiene and 2,3-dimethylbutadiene, or as ene add