1363514-51-5

Basic information

• Product Name: (R)-5-chloro-1-oxo-2,3-dihydro-1H-inden-2-yl benzoate
• CAS NO: 1363514-51-5
• Molecular Weight: 286.715
• Mol File: 1363514-51-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-5-chloro-1-oxo-2,3-dihydro-1H-inden-2-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-5-chloro-1-oxo-2,3-dihydro-1H-inden-2-yl benzoate(1363514-51-5)
• EPA Substance Registry System: (R)-5-chloro-1-oxo-2,3-dihydro-1H-inden-2-yl benzoate(1363514-51-5)

Safety Data

• Hazardous Substances Data: 1363514-51-5(Hazardous Substances Data)

Upstream product

• 42348-86-7 5-chloro-1-indanone 
• 94-36-0 dibenzoyl peroxide 

Relevant articles and documents

Enantioselective α-benzoyloxylation of ketones promoted by primary amine catalyst

A mixture of 9-amino-(9-deoxy)epi-dihydroquinidine and salicylic acid was able to promote the direct reaction of various cyclohexanones with dibenzoyl peroxide, thus affording the corresponding protected α-hydroxy carbonyl compounds in high yield and enantioselectivity. Interestingly the same catalytic salt was found to be active when 1-indanones derivatives were directly employed in the reaction with dibenzoyl peroxide furnishing chiral 1-oxo-2,3-dihydro-1H- inden-2-yl benzoates in high yields and enantioselectivity. Furthermore their treatment with NaBH4 gives easy access to the corresponding enantioenriched 1,2-diols in high yields and without any loss of stereoselectivity.