136430-43-8Relevant articles and documents
Synthesis of β-CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed isomerization
Bizet, Vincent,Pannecoucke, Xavier,Renaud, Jean-Luc,Cahard, Dominique
supporting information, p. 56 - 61 (2013/11/06)
This work describes the optimization process for the synthesis of β-trifluoromethylated ketones from trifluoromethylated allylic alcohols. This transformation proceeds through a ruthenium catalyzed isomerization under mild conditions with high atom econom
The Wittig Reaction of Perfluoro Acid Derivatives: Access to Fluorinated Enol Ethers, Enamines, and Ketones
Begue, Jean-Pierre,Bonnet-Delpon, Daniele,Mesureur, Dany,Nee, Gerard,Wu, Sheng-Wen
, p. 3807 - 3814 (2007/10/02)
The preparation of novel perfluoroalkyl-substituted compounds in good yields is described.This preparation involves the Wittig reaction of a phosphonium ylide with perfluoroalkyl acid derivatives.The influence of the structure of the starting alkylidenetr