13662-06-1

Basic information

• Product Name: Brn 2365009
• Synonyms: 1-(2-Naphthoxy)-2-propanone;1-(2-Naphthyloxy)-2-propanone;2-Naphthyloxyacetone;2-Propanone, 1-(2-naphthyloxy)-;Brn 2365009
• CAS NO: 13662-06-1
• Molecular Formula: C₁₃H₁₂O₂
• Molecular Weight: 200.23318
• Mol File: 13662-06-1.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 342.1°Cat760mmHg
• Flash Point: 158°C
• Appearance: /
• Density: 1.126g/cm³
• Vapor Pressure: 7.68E-05mmHg at 25°C
• Refractive Index: 1.591
• CAS DataBase Reference: Brn 2365009(CAS DataBase Reference)
• NIST Chemistry Reference: Brn 2365009(13662-06-1)
• EPA Substance Registry System: Brn 2365009(13662-06-1)

Safety Data

• Hazardous Substances Data: 13662-06-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H12O2/c1-10(14)9-15-13-7-6-11-4-2-3-5-12(11)8-13/h2-8H,9H2,1H3

Upstream product

• 875-83-2 sodium 2-naphtholate 
• 598-31-2 1-bromoacetone 
• 3698-15-5 2-(allyloxy)naphthalene 
• 135-19-3 β-naphthol 
• 78-95-5 chloroacetone 
• 20009-28-3 naphth-2-yloxymethylacetylene 

Downstream Products

• 883-20-5 9-methylphenanthrene 

Relevant articles and documents

Discovery of oxime-bearing naphthalene derivatives as a novel structural type of Nrf2 activators

Abstract Recent studies have demonstrated that oxidative stress insult is one of major causes of tumor formation. Therefore, identify the effective anti-oxidative agents as a preventive approach to stop cancer progression has widely explored. Although, ma

Catalytic Wacker-type Oxidations Using Visible Light Photoredox Catalysis

A combined palladium/photoredox catalytic system for the efficient oxidation of terminal olefins to the corresponding methyl ketones is presented. The interplay of air, water, and light leads to a protocol in which the stoichiometric oxidants required for oxidative palladium catalysis are substituted with catalytic, single-electron transfer processes. Detailed mechanistic investigations revealed the role of the key components, in situ generated species, and catalysts. A broad range of substrates was examined in homogeneous as well as heterogeneous photoredox protocols, delivering the desired products in good yields.

Synthesis of methyl ketones from terminal olefins using PdCl 2/CrO3 system mimicking the Wacker process

An efficient synthesis of methyl ketones from terminal olefins using PdCl2/CrO3 system mimicking the Wacker process is developed. The method shows good functional groups compatibility, no aldehyde by-products and is operationally simple. CrO3 is the sole oxidant and replaces both Cu-salts and molecular oxygen, traditionally used in this process. The method holds potential for future applications in organic synthesis.