136880-94-9

Basic information

• Product Name: 2H-Azepine, 3,6-bis(1,1-dimethylethyl)-
• CAS NO: 136880-94-9
• Molecular Formula: C14H23N
• Molecular Weight: 205.343
• Mol File: 136880-94-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2H-Azepine, 3,6-bis(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Azepine, 3,6-bis(1,1-dimethylethyl)-(136880-94-9)
• EPA Substance Registry System: 2H-Azepine, 3,6-bis(1,1-dimethylethyl)-(136880-94-9)

Safety Data

• Hazardous Substances Data: 136880-94-9(Hazardous Substances Data)

Upstream product

• 87086-78-0 methyl 3,6-di-tert-butyl-1H-azepine-1-carboxylate 

Relevant articles and documents

Synthesis and Characterization of 2H-, 3H- and 4H-Azepine: The First Observation of the Thermal Distribution Equilibrium of Azepines

Demethoxycarbonylation of methyl 2,5-di-tert-butyl-1H-azepine-1-carboxylate using 1,8-diazabicycloundec-7-ene gives exclusively two isomers of 3H-azepine derivatives, while methyl 3,6-di-tert-butyl-1H-azepine-1-carboxylate gives a mixture of 2H-, 3H- and 4H-azepine derivatives under the same conditions because of a 1,5-hydrogen shift in the resulting triene system.