136914-86-8

Basic information

• Product Name: 3-<4-(tetrahydro-2-pyranyloxy)butyl>-2-cyclohexen-1-one
• Synonyms: 3-<4-(tetrahydro-2-pyranyloxy)butyl>-2-cyclohexen-1-one
• CAS NO: 136914-86-8
• Molecular Weight: 252.354
• Mol File: 136914-86-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-<4-(tetrahydro-2-pyranyloxy)butyl>-2-cyclohexen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-<4-(tetrahydro-2-pyranyloxy)butyl>-2-cyclohexen-1-one(136914-86-8)
• EPA Substance Registry System: 3-<4-(tetrahydro-2-pyranyloxy)butyl>-2-cyclohexen-1-one(136914-86-8)

Safety Data

• Hazardous Substances Data: 136914-86-8(Hazardous Substances Data)

Upstream product

• 23074-59-1 3-isobutoxycyclohex-2-en-1-one 
• 58766-02-2 4-<(tetrahydropyran-2-yl)oxy>butylmagnesium chloride 
• 41302-05-0 1-chloro-4-tetrahydropyranyloxybutane 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 

Relevant articles and documents

Studies towards the synthesis of crotogoudin

An effective synthesis of the tricyclic core structure of the new diterpene crotogoudin was achieved. The synthesis features an intermolecular domino Michael reaction to construct a bicyclo[2.2.2]octane motif and an aldol condensation to close ring B. Stork reductive alkylation with allyl bromide proceeded from the β side, resulting in the wrong stereochemistry at C-10. Georg Thieme Verlag Stuttgart - New York.

Photochemistry of α,β-Unsaturated γ,δ-Epoxy Nitrile: A New Methodology for Synthesis of Spiroketals

Photoinduced intramolecular cyclization of δ-hydroxybutyl-α,β-unsaturated γ,δ-epoxy nitriles 5a, b provides rapid access to the spiro ketal skeleton.