1370085-01-0

Basic information

• Product Name: [Rh(CO)(PPh₃)3][K(18-crown-6)]
• Synonyms: [Rh(CO)(PPh₃)3][K(18-crown-6)]
• CAS NO: 1370085-01-0
• Molecular Weight: 1221.21
• Mol File: 1370085-01-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Rh(CO)(PPh₃)3][K(18-crown-6)](CAS DataBase Reference)
• NIST Chemistry Reference: [Rh(CO)(PPh₃)3][K(18-crown-6)](1370085-01-0)
• EPA Substance Registry System: [Rh(CO)(PPh₃)3][K(18-crown-6)](1370085-01-0)

Safety Data

• Hazardous Substances Data: 1370085-01-0(Hazardous Substances Data)

Upstream product

• 17185-29-4 carbonylhydridetris(triphenylphosphine)rhodium(I) 
• 17455-13-9 18-crown-6 ether 

Downstream Products

• 17185-29-4 carbonylhydridetris(triphenylphosphine)rhodium(I) 

Relevant articles and documents

Synthesis of rhodaboratranes bearing phosphine-tethered boranes: Evaluation of the metal-boron interaction

A series of rhodaboratranes [{o(Ph2P)C6H 4}3BRhHn(CO)]m (1, n = 1, m = 0; 4, n = 0, m = +1; 5, n = 0, m = -1) with different electron charges ranging from -1 to +1 have been synthesized. X-ray diffraction, IR, NMR, and DFT calculation studies have demonstrated that the σ-acceptor borane ligand produces a unique electron distribution in these systems and significantly weakens the Rh-L bond (L = CO, PR3) trans to the boron. The reversible CO/PR 3 (R = Me or Ph) substitution reactions of 1 and 5 are attributed to these properties.