137024-35-2Relevant articles and documents
Ruthenium nanoparticle-catalyzed, controlled and chemoselective hydrogenation of nitroarenes using ethanol as a hydrogen source
Kim, Ju Hyun,Park, Ji Hoon,Chung, Young Keun,Park, Kang Hyun
, p. 2412 - 2418 (2012)
This communication describes a ruthenium nanoparticle-catalyzed reduction of nitroarenes giving azoxyarenes, azoarenes, or anilines in good to excellent yields using ethanol as a hydrogen source. Copyright
Impact of the Alkyne Substitution Pattern and Metalation on the Photoisomerization of Azobenzene-Based Platinum(II) Diynes and Polyynes
Al-Balushi, Rayya A.,Haque, Ashanul,Jayapal, Maharaja,Al-Suti, Mohammed K.,Husband, John,Khan, Muhammad S.,Skelton, Jonathan M.,Molloy, Kieran C.,Raithby, Paul R.
, p. 10955 - 10967 (2016)
Trimethylsilyl-protected dialkynes incorporating azobenzene linker groups, Me3SiC ≡ CRC ≡ CSiMe3 (R = azobenzene-3,3′-diyl, azobenzene-4,4′-diyl, 2,5-dioctylazobenzene-4,4′-diyl), and the corresponding terminal dialkynes, HC ≡ CRC ≡
Organocatalytic oxidative dehydrogenation of aromatic amines for the preparation of azobenzenes under mild conditions
Ma, Hengchang,Li, Wenfeng,Wang, Jian,Xiao, Guanghai,Gong, Yuan,Qi, Chunxuan,Feng, Yunpeng,Li, Xiufang,Bao, Zhikang,Cao, Wei,Sun, Qiangsheng,Veaceslav, Caraus,Wang, Feng,Lei, Ziqiang
experimental part, p. 8358 - 8366 (2012/09/21)
(Diacetoxyiodo)benzene used as stoichiometrically and catalytically in the preparation of azobenzenes under mild reaction conditions was developed. The metal-free oxidation systems demonstrated wide substituents tolerance, alkyls, halogens, and several versatile functional groups, such as amino, ethynyl, and carboxyl substituents are compatible well, and the corresponding products could be formed with good to excellent yields. In this disclosed method, the more large scale formation of azo compounds also could be carried out successfully. Of note that 3-ethynylbenzenamine applied as a very useful cross dehydrogenative partner, which coupled with different anilines, providing asymmetrical azo compounds with acceptable yields in one step under very mild reaction conditions.
