1370458-09-5

Basic information

• Product Name: C₄₇H₄₇BrCl₄N₈O₁₀Si
• Synonyms: C₄₇H₄₇BrCl₄N₈O₁₀Si
• CAS NO: 1370458-09-5
• Molecular Weight: 1133.74
• Mol File: 1370458-09-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₄₇H₄₇BrCl₄N₈O₁₀Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₇H₄₇BrCl₄N₈O₁₀Si(1370458-09-5)
• EPA Substance Registry System: C₄₇H₄₇BrCl₄N₈O₁₀Si(1370458-09-5)

Safety Data

• Hazardous Substances Data: 1370458-09-5(Hazardous Substances Data)

Upstream product

• 93299-38-8 L-5-bromotryptophan methyl ester 
• 4299-70-1 L-tryptophan methyl ester 
• 189256-58-4 (S)-2-{[1-(4-Chloro-3-nitro-phenyl)-meth-(E)-ylidene]-amino}-succinamic acid tert-butyl ester 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 66377-68-2 N-(methoxycarbonyl)-L-tryptophan methyl ester 
• 1370458-22-2 dimethyl (2S,3aR,8aS)-8-acetyl-5-bromo-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-1,2-dicarboxylate 
• 1370458-21-1 dimethyl (2S,3aR,8aS)-8-acetyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-1,2-dicarboxylate 
• 1392222-60-4 (S)-3-((tert-butoxycarbonyl)amino)-2-((tert-butyldiphenylsilyl)oxy)propanoic acid 
• 1370458-08-4 C₅₆H₆₅BrCl₄N₈O₁₃Si 
• 1370458-26-6 C₃₆H₃₅Cl₄N₅O₁₀ 
• 1370458-16-4 C₂₁H₂₅Cl₄N₅O₈ 
• 1370458-05-1 Boc-Ise(TBDPS)-Trp(5-Br)-OH 
• 1370458-23-3 Boc-Ise(TBDPS)-Trp(5-Br)-OMe 
• 1159016-08-6 methyl (S)-3-((tert-butoxycarbonyl)amino)-2-((tert-butyldiphenylsilyl)oxy)propanoate 

Relevant articles and documents

Total synthesis of nominal (11S)- and (11R)-cyclocinamide A

The cyclocinamides possess a unique β2αβ 2α 14-membered tetrapeptide core. The initially reported biological data and intriguing structure, which was without full stereochemical identification, necessitated synthesis of both nominal (all-S) cyclocinamide A and the 11R isomer. The completed synthesis is highlighted by the use of a (cyclo)asparagine-containing dipeptide as a turn inducing fragment. Due to inconsistencies in analytical data between natural and synthetic samples, a re-evaluation of the natural product stereochemistry appears necessary.