137114-69-3Relevant articles and documents
Pd-catalyzed aerobic direct olefination of polyfluoroarenes
He, Chun-Yang,Qing, Feng-Ling,Zhang, Xingang
supporting information, p. 2962 - 2964 (2014/05/06)
The first example of Pd-catalyzed aerobic direct olefination of polyfluoroarenes has been developed. The reaction makes use of molecular O 2 as terminal oxidant, and provides a cost-efficient and environmentally benign access to polyfluoroarene-alkene structures that are of interest in life and material sciences.
Development of a decarboxylative palladation reaction and its use in a Heck-type olefination of arene carboxylates
Myers, Andrew G.,Tanaka, Daisuke,Mannion, Michael R.
, p. 11250 - 11251 (2007/10/03)
The development of a palladium-catalyzed decarboxylative coupling reaction of arene carboxylates with olefinic substrates is described. The optimized procedure for decarboxylative palladation employs Pd(O2CCF3)2 as catalys