1373029-09-4

Basic information

• Product Name: ethyl 2-chloro-4-formylbenzoate
• CAS NO: 1373029-09-4
• Molecular Weight: 212.633
• Mol File: 1373029-09-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 323.5±27.0 °C(Predicted)
• Density: 1.269±0.06 g/cm3(Predicted)
• CAS DataBase Reference: ethyl 2-chloro-4-formylbenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-chloro-4-formylbenzoate(1373029-09-4)
• EPA Substance Registry System: ethyl 2-chloro-4-formylbenzoate(1373029-09-4)

Safety Data

• Hazardous Substances Data: 1373029-09-4(Hazardous Substances Data)

Upstream product

• 99500-35-3 ethyl 2-chloro-4-methylbenzoate 

Relevant articles and documents

Development of a Rhodium(II)-Catalyzed Chemoselective C(sp3)-H Oxygenation

We report the first example of RhII-catalyzed chemoselective double C(sp3)-H oxygenation, which can directly transform various toluene derivatives into highly valuable aromatic aldehydes with great chemoselectivity and practicality. The critical combination of catalyst Rh(OAc)2, oxidant Selectfluor, and solvents of TFA/TFAA promises the successful delivery of the oxidation with satisfactory yields. A possible mechanism involving a unique carbene-Rh complex is proposed, and has been supported by both experiments and theoretical calculations.