137303-14-1

Basic information

• Product Name: Cyclohexanemethanol, 2-(methoxymethyl)-, trans-
• CAS NO: 137303-14-1
• Molecular Formula: C9H18O2
• Molecular Weight: 158.241
• Mol File: 137303-14-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclohexanemethanol, 2-(methoxymethyl)-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanemethanol, 2-(methoxymethyl)-, trans-(137303-14-1)
• EPA Substance Registry System: Cyclohexanemethanol, 2-(methoxymethyl)-, trans-(137303-14-1)

Safety Data

• Hazardous Substances Data: 137303-14-1(Hazardous Substances Data)

Upstream product

• 110-83-8 cyclohexene 
• 50-00-0 formaldehyd 
• 18964-35-7 trans-1-methoxymethyl-2-chlorocyclohexane 
• 76155-27-6 (+/-)-trans-2-(hydroxymethyl)cyclohexylmethanol 
• 74-88-4 methyl iodide 

Downstream Products

• 137303-15-2 trans-1-methoxymethyl-2-chloromethylcyclohexane 
• 13149-01-4 cis-8-oxabicyclo<4.3.0>nonane 
• 4743-54-8 trans-8-oxabicyclo<4.3.0>nonane 
• 138043-12-6 cis-3-phenyl-trans-2-oxadecalin 
• 138043-08-0 2-((1R,2S)-2-Methoxymethyl-cyclohexyl)-1-phenyl-ethanol 
• 138043-07-9 trans-1-methoxymethyl-2-(2-hydroxypentyl)cyclohexane 
• 138043-06-8 1-((1R,2S)-2-Methoxymethyl-cyclohexyl)-butan-2-ol 
• 138043-05-7 1-((1S,2R)-2-Methoxymethyl-cyclohexyl)-propan-2-ol 

Relevant articles and documents

Formation of cyclic sulfonium salts by Me3SiI-promoted intramolecular displacement of hydroxide or methoxide by sulfide. Ring contraction thiepane → thiolane

A suitably positioned (1,2-, 1,4-, and 1,5-) intramolecular sulfide interferes with the iodotrimethylsilane-promoted iodine for hydroxyl substitution, as well as the related alcohol deprotection procedure (regioselective cleavage of methyl ethers). The ou