1373406-69-9

Basic information

• Product Name: 1-{1-[(4-methylcoumarin-7-yl)thio]-4-bromo-3,4-dichloro-2-nitro-1,3-butadienyl}-4-(4-nitrophenyl)piperazine
• CAS NO: 1373406-69-9
• Molecular Weight: 642.314
• Mol File: 1373406-69-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-{1-[(4-methylcoumarin-7-yl)thio]-4-bromo-3,4-dichloro-2-nitro-1,3-butadienyl}-4-(4-nitrophenyl)piperazine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-{1-[(4-methylcoumarin-7-yl)thio]-4-bromo-3,4-dichloro-2-nitro-1,3-butadienyl}-4-(4-nitrophenyl)piperazine(1373406-69-9)
• EPA Substance Registry System: 1-{1-[(4-methylcoumarin-7-yl)thio]-4-bromo-3,4-dichloro-2-nitro-1,3-butadienyl}-4-(4-nitrophenyl)piperazine(1373406-69-9)

Safety Data

• Hazardous Substances Data: 1373406-69-9(Hazardous Substances Data)

Upstream product

• 137215-27-1 7-mercapto-4-methyl-2H-chromen-2-one 
• 6269-89-2 1-(4-Nitrophenyl)piperazine 
• 1373406-59-7 4-bromo-1,3,4-trichloro-2-nitro-1-[(4-methylcoumarin-7-yl)thio]-1,3-butadiene 

Relevant articles and documents

The synthesis of N,S-substituted compounds from the reactions of 2-nitrohalobuta-1,3-diene with mercaptocoumarin

4-Bromo-1,3,4-trichloro-2-nitro-1-(7-coumarinthio-4-methyl)-1,3-butadiene (3), and 4-Bromo-3,4-dichloro-2-nitro-1,1-bis (7-coumarinthio-4-methyl)-1,3- butadiene (4) were synthesized from the reactions of 4-bromo-1,1,3,4- tetrachloro-2-nitro-1,3-butadiene (1) with 7-mercapto-4- methylcoumarin (2). Afterwards, new N,S- substituted dienes( 6a-j, 8a-d, 10 and 12) were obtained by the reactions of derivatives of piperazine [4-(fluorophenyl) piperazine, phenyl piperazine, 1-(2-methoxyphenyl)-piperazine, ethoxycarbonyl piperazine, formylpiperazine,2-(fluorophenyl)- piperazine, 4-(nitrophenyl)-piperazine, diphenylmethyl piperazine, 4-(hydroxyphenyl)- piperazine, 4-(hydroxyphenyl)- piperazine]; piperidine [4-methyl piperidinyl, 4-benzyl piperidinyl, 4-hydroxy piperidinyl]; morpholin and 1,4-dioxoazospiro [4,5] decan with the mono(thio)substituted nitrodien compound 3. Structures of the novel compounds were characterized by using microanalysis, FT-IR, UV-Vis, 1HNMR, APT and MS spectroscopy methods.