1373436-69-1Relevant articles and documents
Ligand-free iron-catalyzed benzylic C (sp3)-H amination of methylarenes with: N -fluorobenzenesulfonimide
Bao, Fengyu,Cao, Yuanbo,Liu, Wenbo,Zhu, Junhao
, p. 27892 - 27895 (2019/09/30)
Direct conversion of cheap methylarenes to benzylic amines, which are essential structural units of important drugs, is of great significance. However, the known methodologies suffer from the requirement of noble metal catalysts, heavy metal residues or s
Palladium-Catalyzed Intermolecular Oxidative Diazidation of Alkenes
Peng, Haihui,Yuan, Zheliang,Chen, Pinhong,Liu, Guosheng
supporting information, p. 876 - 880 (2017/06/27)
A palladium-catalyzed oxidative vicinal diazidation of alkenes has been developed, in which TMSN3 was used as azide source. Both styrenes and unactivated alkenes are suitable for this reaction. And trans-alkyldiazides were obtained as major products from cyclic alkenes with moderate to good diastereoselectivities. This reaction afforded an efficient way for the synthesis of useful 1,2-diamines after hydrogenation.
Palladium-catalyzed intermolecular C(sp3)-H amidation
Iglesias, Alvaro,Alvarez, Rosana,De-Lera, Angel R.,Muniz, Kilian
supporting information; experimental part, p. 2225 - 2228 (2012/04/10)
Dual capacity: A new palladium-catalyzed intermolecular sequence consisting of the C-H activation and amidation of methyl groups relies on N-fluorobis(phenylsulfonyl)imide (NFSI) as both the oxidant and the nitrogen source. The reaction provides the corresponding arylamines as bissulfonimides along with HF as the only by-product. Both experimental and computational results suggest the involvement of a monomeric palladium(IV) intermediate. Copyright
