1373945-24-4Relevant articles and documents
Palladium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzosiloles via enantioselective C-H bond functionalization
Shintani, Ryo,Otomo, Haruka,Ota, Kensuke,Hayashi, Tamio
, p. 7305 - 7308 (2012/06/16)
A Pd-catalyzed asymmetric synthesis of Si-stereogenic dibenzosiloles is developed through enantioselective C-H bond functionalization of prochiral 2-(arylsilyl)aryl triflates. High chemo- and enantioselectivities are achieved by employing a Josiphos-type ligand under mild conditions.