137406-90-7

Basic information

• Product Name: N-benzylidene<α-(benzotriazol-1-yl)benzyl>amine
• Synonyms: N-benzylidene<α-(benzotriazol-1-yl)benzyl>amine
• CAS NO: 137406-90-7
• Molecular Weight: 312.374
• Mol File: 137406-90-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-benzylidene<α-(benzotriazol-1-yl)benzyl>amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzylidene<α-(benzotriazol-1-yl)benzyl>amine(137406-90-7)
• EPA Substance Registry System: N-benzylidene<α-(benzotriazol-1-yl)benzyl>amine(137406-90-7)

Safety Data

• Hazardous Substances Data: 137406-90-7(Hazardous Substances Data)

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 100-52-7 benzaldehyde 

Downstream Products

• 138212-05-2 (3R,3aS,7aR)-1,3-Diphenyl-3,3a,5,6,7,7a-hexahydro-isoindol-4-one 
• 138212-04-1 (2S,3S,4S)-2,5-Diphenyl-3,4-dihydro-2H-pyrrole-3,4-dicarboxylic acid diethyl ester 
• 138212-06-3 1,3-Diphenyl-3a,7a-dihydro-1H-isoindole-4,7-dione 
• 13901-70-7 dimethyl 2,5-diphenyl-1H-pyrrole-3,4-dicarboxylate 
• 31697-95-7 (2S,3R)-2,5-Diphenyl-3,4-dihydro-2H-pyrrole-3-carboxylic acid methyl ester 
• 28168-60-7 (2S,3S)-2,5-Diphenyl-3,4-dihydro-2H-pyrrole-3-carbonitrile 
• 103-49-1 dibenzylamine 
• 137406-99-6 bis(α-benzylbenzyl)amine 
• 138212-04-1 (2R,3S,4S)-2,5-Diphenyl-3,4-dihydro-2H-pyrrole-3,4-dicarboxylic acid diethyl ester 
• 107554-57-4 3a-cis-3a,4-trans-1,2,3,3a,4,6a-hexahydro-2-methyl-1,3-dioxo-4,6-diphenylpyrrolo<3,4-c>pyrrole 
• 107554-57-4 3a-cis-3a,4-cis-1,2,3,3a,4,6a-hexahydro-2-methyl-1,3-dioxo-4,6-diphenylpyrrolo<3,4-c>pyrrole 

Relevant articles and documents

The synthesis of pyrroles and dihydropyrroles by 1,3-dipolar cyclisations of N-arylmethylene[(benzotriazol-1-yl)arylmethyl]amines

N-Arylmethylene[(benzotriazol-1-yl)arylmethyl]amines 1 are prepared by the reaction of arylaldehydes, benzotriazole, and ammonia in dry ethanol. Deprotonation of these imines with butyllithium yields N-lithiated azomethine ylides 2 which readily undergo 1,3-dipolar cycloaddition with a large range of dipolarophiles. The cyclisations are regiospecific and generally exhibit high stereoselectivity. Benzotriazolate is eliminated during the course of the reaction, and the method thereby provides a route to 2,5-diaryl substituted pyrroles, 3,4-dihydro-2H-pyrroles and c-ring fused 3,4-dihydro-2H-pyrroles.