1374152-38-1

Basic information

• Product Name: 1-(1-azidovinyl)-4-fluorobenzene
• Synonyms: 1-(1-azidovinyl)-4-fluorobenzene
• CAS NO: 1374152-38-1
• Molecular Weight: 163.154
• Mol File: 1374152-38-1.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: 1-(1-azidovinyl)-4-fluorobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-azidovinyl)-4-fluorobenzene(1374152-38-1)
• EPA Substance Registry System: 1-(1-azidovinyl)-4-fluorobenzene(1374152-38-1)

Safety Data

• Hazardous Substances Data: 1374152-38-1(Hazardous Substances Data)

Upstream product

• 350-35-6 1-(1,2-dibromoethyl)-4-fluorobenzene 
• 405-99-2 para-fluorostyrene 

Downstream Products

• 75738-80-6 (+)-(S)-γ-(4-fluorophenyl)-γ-butyrolactone 
• 1414365-78-8 1-benzyl-4-(4-fluorophenyl)-2-phenyl-1H-imidazole 
• 369-41-5 2-fluoro-1-(4-fluorophenyl)ethanone 
• 1401518-57-7 2-(4-fluorophenyl)-1-(pyridin-2-yl)-1H-indole 
• 77815-14-6 2-amino-4-(4-fluorophenyl)thiazole 

Relevant articles and documents

Rhodium-Catalyzed Double Isocyanide Insertion via a Vinylcarbodiimide Intermediate for the Synthesis of 2H-Pyrrol-2-imines

2 H -Pyrrol-2-imine is an important structural motif exhibiting in biologically active compounds and natural products. An efficient rhodium-catalyzed one-pot reaction of one vinyl azide with sequentially with two different isocyanides is reported, which offers an alternative facile access to 3-amino-5-aryl-2 H -pyrrol-2-imines bearing various substitution on the nitrogens in good yields. An unstable vinylcarbodiimide is the key intermediate in this cascade reaction.

Electrosynthesis of N-unsubstituted enaminosulfones from vinyl azides and sodium sulfinates mediated by NH4I

A wide range of N-unsubstituted enaminosulfones were obtained via electrochemical sulfonylation of vinyl azides with sulfonyl radicals generated from sodium sulfinates. The discovery of N-unsubstituted enaminosulfones synthesis is based on a unique ability of the azido group to eliminate the N2 molecule. The process is performed under constant current conditions in an experimentally convenient undivided electrochemical cell equipped with a graphite anode and a stainless steel cathode applying NH4I both as the redox catalyst and the supporting electrolyte.

Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides

Sulfonylated N-unsubstituted enamines were synthesized through a chain of chemical and electrochemical transformations via sulfonylation of vinyl azides. The disclosing of the N-unsubstituted enamines synthesis was based on a unique property of the azido group, which is its ability to eliminate the N2 molecule. Furthermore, a formal paradox is observed: A double bond reacts and a double bond is retained. Electrosynthesis proceeded in an undivided cell equipped with a graphite anode and a stainless steel cathode; NH4I was used as a supporting electrolyte.