1375077-59-0

Basic information

• Product Name: 1-benzoyloxy-3-allyloxypropan-2-one
• Synonyms: 1-benzoyloxy-3-allyloxypropan-2-one
• CAS NO: 1375077-59-0
• Molecular Weight: 234.252
• Mol File: 1375077-59-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-benzoyloxy-3-allyloxypropan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-benzoyloxy-3-allyloxypropan-2-one(1375077-59-0)
• EPA Substance Registry System: 1-benzoyloxy-3-allyloxypropan-2-one(1375077-59-0)

Safety Data

• Hazardous Substances Data: 1375077-59-0(Hazardous Substances Data)

Upstream product

• 73097-87-7 2-hydroxy-3-(prop-2-en-1-yloxy)propyl benzoate 

Downstream Products

• 123-34-2 (S)-3-allyloxy-propane-1,2-diol 
• 123-34-2 (R)-3-allyloxypropane-1,2-diol 
• 1375077-63-6 (S)-MTPA ester of (R)-1-acetoxy-3-allyloxypropan-2-ol 
• 1375077-62-5 (R)-MTPA ester of (R)-1-acetoxy-3-allyloxypropan-2-ol 

Relevant articles and documents

Enzymatic synthesis of both enantiomeric forms of 3-allyloxy-propane-1,2- diol

The stereoselective synthesis of (S)- and (R)-3-allyloxy-propane-1,2-diol has been accomplished in four steps from (RS)-3-allyloxy-propane-1,2-diol. Only one intermediate, namely 1-benzoyloxy-3-allyloxy-2-propanone has been prepared by a chemical reaction, that is, pyridinium chlorochromate oxidation of 1-benzoyloxy-3-allyloxypropan-2-ol. All of the remaining reactions (regioselective acylations, asymmetric bioreduction of prochiral ketones, and enzymatic alcoholysis) have been carried out in the presence of biocatalysts.