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137512-74-4

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137512-74-4 Usage

Description

(4''R)-4''-DEOXY-4''-(METHYLAMINO)AVERMECTIN B1 BENZOATE, also known as Emamectin Benzoate, is a semi-synthetic derivative of the Avermectin class of compounds. It is a white crystalline powder that exists in various hydrated forms with different crystal morphologies. (4''R)-4''-DEOXY-4''-(METHYLAMINO)AVERMECTIN B1 BENZOATE is primarily used as an insecticide due to its high effectiveness against a broad range of lepidopteran larvae and certain other insects.

Uses

Used in Agricultural Industry:
(4''R)-4''-DEOXY-4''-(METHYLAMINO)AVERMECTIN B1 BENZOATE is used as an insecticide for controlling pests in agriculture. It is particularly effective against lepidopteran larvae, which are the caterpillar stage of various butterfly and moth species, as well as certain other insects that can cause significant damage to crops.
Used in Environmental Pest Control:
(4''R)-4''-DEOXY-4''-(METHYLAMINO)AVERMECTIN B1 BENZOATE is also used in environmental pest control to manage insect populations that can cause damage to plants, trees, and other vegetation. Its broad-spectrum activity makes it a valuable tool for protecting the health and appearance of landscapes and gardens.
Used in Veterinary Medicine:
In addition to its use in agriculture and environmental pest control, (4''R)-4''-DEOXY-4''-(METHYLAMINO)AVERMECTIN B1 BENZOATE is utilized in veterinary medicine for the treatment and prevention of various parasitic infections in animals. Its effectiveness against a wide range of insects makes it a valuable asset in maintaining the health of livestock and pets.

Metabolic pathway

In laboratory studies, emamectin benzoate is relatively stable to aqueous hydrolysis (acid, neutral and alkaline) under dark conditions. Emamectin benzoate degrades extensively in soil via microbial action to multiple degradation products including the 8a-oxidation and 8a-hydroxylation products. CO2 and soil-bound residues were the major terminal residues which are incorporated into humic and fulvic acid fractions. In plants, emamectin benzoate degrades extensively to multiple polar components including the N-demethylated, N-formylated and conjugated products. Probably due to rapid elimination in faeces, the metabolic transformation of emamectin benzoate in animals is minimal. However, N-demethylation was observed as the major metabolic pathway. The hydrolytic, photolytic and overall metabolic pathways of emamectin benzoate in soils, plants and animals are presented in Schemes 1,2 and 3.

Degradation

Emamectin benzoate (1) was relatively stable to hydrolysis in acidic, neutral and alkaline solutions (pH 5, 7 and 9) at 25 °C, with less than 10% degradation occurring after 30 days. It hydrolysed most rapidly in acidic solution (pH 5) at 25 °C with a DT50 of 136 days (Chukwudebe, 1992). Two polar components (each <10%) eluted close to the void volume under reversed phase chromatographic conditions. The photodegradation half-lives of emamectin benzoate (10-12 mg 1-1) in buffered distilled water (pH 7) containing 1% (v/v) acetonitrile, ethanol or acetone as cosolvent under continuous exposure to a xenon lamp were 65,9 and 0.5 days, respectively. In both buffered and natural pond water, the major photodegradation products included 8,9-MAB1a (2), 8a-hydroxylated MAB1a (3) and minor unknown polar residues (Scheme 1). In sensitised buffered water, 8a-oxo-MAB1a (4) and 10,11-14,15-MAB1a diepoxide (5) were found as additional residual products (Mushtaq et al., 1997).

Check Digit Verification of cas no

The CAS Registry Mumber 137512-74-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,7,5,1 and 2 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 137512-74:
(8*1)+(7*3)+(6*7)+(5*5)+(4*1)+(3*2)+(2*7)+(1*4)=124
124 % 10 = 4
So 137512-74-4 is a valid CAS Registry Number.
InChI:InChI=1/C49H75NO13.C7H6O2/c1-12-26(2)44-29(5)18-19-48(63-44)24-35-21-34(62-48)17-16-28(4)43(27(3)14-13-15-33-25-56-46-42(51)30(6)20-36(47(52)59-35)49(33,46)53)60-40-23-38(55-11)45(32(8)58-40)61-39-22-37(54-10)41(50-9)31(7)57-39;8-7(9)6-4-2-1-3-5-6/h13-16,18-20,26-27,29,31-32,34-46,50-51,53H,12,17,21-25H2,1-11H3;1-5H,(H,8,9)/b14-13+,28-16+,33-15+;/t26?,27-,29-,31-,32-,34+,35-,36-,37-,38-,39?,40?,41-,42+,43-,44+,45-,46+,48+,49+;/m0./s1

137512-74-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Emamectin Benzoate

1.2 Other means of identification

Product number -
Other names AKOS015950774

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:137512-74-4 SDS

137512-74-4Upstream product

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