137569-28-9

Basic information

• Product Name: t-butyl (2S,5S,1'R)-2-(t-butyl)-5-<2'-(2,6-di-t-butyl-4-methoxyphenoxycarbonyl)-1'-ethylethyl>-3-methyl-4-oxo-1-imidazolidinecarboxylate
• CAS NO: 137569-28-9
• Molecular Weight: 574.802
• Mol File: 137569-28-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: t-butyl (2S,5S,1'R)-2-(t-butyl)-5-<2'-(2,6-di-t-butyl-4-methoxyphenoxycarbonyl)-1'-ethylethyl>-3-methyl-4-oxo-1-imidazolidinecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: t-butyl (2S,5S,1'R)-2-(t-butyl)-5-<2'-(2,6-di-t-butyl-4-methoxyphenoxycarbonyl)-1'-ethylethyl>-3-methyl-4-oxo-1-imidazolidinecarboxylate(137569-28-9)
• EPA Substance Registry System: t-butyl (2S,5S,1'R)-2-(t-butyl)-5-<2'-(2,6-di-t-butyl-4-methoxyphenoxycarbonyl)-1'-ethylethyl>-3-methyl-4-oxo-1-imidazolidinecarboxylate(137569-28-9)

Safety Data

• Hazardous Substances Data: 137569-28-9(Hazardous Substances Data)

Upstream product

• 75169-17-4 4-acetoxy-3,5-di-tert-butylanisole 
• 489-01-0 2,6-Di-t-butyl-4-methoxyphenol 
• 137569-21-2 2,6-di-t-butyl-4-methoxyphenyl 2-pentenoate 
• 119838-38-9 (2S)-1-(tert-butyloxycarbonyl)-2-tert-butyl-3-methylimidazolidin-4-one 

Relevant articles and documents

threo-3-Alkyl- and -Arylglutamic Acid Derivatives by Michael Additions of Boc-BMI Li-Enolates to 2,6-Di-t-butyl-4-methoxyphenyl Alkenoates On the Diastereoselectivity of the Coupling of Trigonal Centers Involving Heterocyclic Li-Enolates

The conjugated esters 5, 6, 8, 9 mentioned in the title are prepared from the corresponding aryl acetate 4 and aldehydes by aldol condensation (direct enoylation of the hindered phenol with the corresponding unsaturated acid chlorides gave only poor yield