13779-49-2Relevant articles and documents
Fluoridolysis of Diphosphoryl Compounds
Loewe, C.,Pauli, J.,Riesel, L.
, (2008/10/08)
The behaviour of diphosphoryl compounds [X2(O)P]2Y in fluoridolysis reactions is decisively determinated by the nature of the bridging group Y. In the cases of Y=NH and CH2 and X=Cl [F2P(O)]2N(1-) and [F2P(O)]2CH2 are obtained quantitatively. For Y=NPh, O, and CH3 the formation of phosphrylated pentafluorophosphates [F5P-Y-POX2](1-) is observed. Amido and ester derivatives containing fluorine (see table 2) are obtained from the corresponding chloro compounds by Cl/F exchange. Fluoridolysis of the azadiphosphetidine 19 results in the formation of acyclic 19a.
