137812-27-2Relevant articles and documents
REACTIONS OF POLYFLUORO AROMATIC COMPOUNDS WITH ELECTROPHILIC AGENTS IN THE PRESENCE OF TRIS(DIALKYLAMINO)PHOSPHINES. I. SYNTHESIS OF TRIALKYLSILYL(GERMYL, STANNYL, OR PLUMBYL)POLYFLUOROBENZENES
Bardin, V. V.,Pressman, L. S.,Rogoza, L. N.,Furin, G. G.
, p. 1931 - 1937 (2007/10/02)
Polyfluorophenyl bromides and iodides react with alkylhalo derivatives of silicon, germanium, tin, or lead in the presence of equimolar amounts of a tris(dialkylamino)phosphine to give polyfluorophenyl(alkyl) derivatives of the above-mentioned elements and phosphonium salts.Electron-donor substituents in position 4 of the polyfluorophenyl bromide slow down the reaction, while electron-acceptor substituents accelerate it.