137897-38-2

Basic information

• Product Name: Silane, [(3-azido-1-cyclohexen-1-yl)oxy]tris(1-methylethyl)-
• CAS NO: 137897-38-2
• Molecular Formula: C15H29N3OSi
• Molecular Weight: 295.5
• Mol File: 137897-38-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silane, [(3-azido-1-cyclohexen-1-yl)oxy]tris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(3-azido-1-cyclohexen-1-yl)oxy]tris(1-methylethyl)-(137897-38-2)
• EPA Substance Registry System: Silane, [(3-azido-1-cyclohexen-1-yl)oxy]tris(1-methylethyl)-(137897-38-2)

Safety Data

• Hazardous Substances Data: 137897-38-2(Hazardous Substances Data)

Upstream product

• 128-37-0 2,6-di-tert-butyl-4-methyl-phenol 
• 80522-46-9 1-triisopropylsiloxy-1-cyclohexene 

Downstream Products

• 153789-77-6 3-Triisopropylsilanyloxy-cyclohex-2-enylamine 
• 140677-70-9 1-Triisopropylsilanyloxy-3-trimethylsilanylethynyl-cyclohexene 
• 935758-78-4 3-(1H-indol-3-yl)cyclohexanone 
• 145147-29-1 Triisopropyl-(3-methyl-cyclohex-1-enyloxy)-silane 
• 153789-83-4 (E)-3-(4-Nitro-phenyl)-N-(3-triisopropylsilanyloxy-cyclohex-2-enyl)-acrylamide 
• 153789-89-0 (E)-3-(3-Triisopropylsilanyloxy-cyclohex-2-enylcarbamoyl)-acrylic acid ethyl ester 
• 153789-82-3 (E)-3-Phenyl-N-(3-triisopropylsilanyloxy-cyclohex-2-enyl)-acrylamide 
• 153789-78-7 N-(3-Triisopropylsilanyloxy-cyclohex-2-enyl)-acrylamide 
• 142683-27-0 1'-Azido-3'-triisopropylsilanyloxy-bicyclohexyl-2'-en-2-one 
• 142683-28-1 3-(2-oxo-cyclohexanyl)-2-cyclohexene-1-one 
• 140677-76-5 [((E)-3-Hex-1-enyl)-cyclohex-1-enyloxy]-triisopropyl-silane 
• 140677-75-4 Triisopropyl-[3-((E)-styryl)-cyclohex-1-enyloxy]-silane 
• 133381-98-3 Triisopropyl-(3-phenylethynyl-cyclohex-1-enyloxy)-silane 
• 140677-67-4 3-Triisopropylsilanyloxy-cyclohex-2-enecarbonitrile 

Relevant articles and documents

New Trialkylsilyl Enol Ether Chemistry: Direct 1,2-Bis-azidonation of Triisopropylsilyl Enol Ethers: an Azido-radical Addition Process Promoted by TEMPO

Treatment of triisopropylsilyl enol ethers with PhIO/TMSN3/TEMPO(cat.) -45 deg C results in 1,2-bis-azidonation, which appears to occur through a radical addition process; the 1-azido group can be replaced by carbon nucleophiles such as allyl,

Hypervalent iodine chemistry: New oxidation reactions using the iodosylbenzene-trimethylsilyl azide reagent combination. Direct α- and β-azido functionalization of triisopropylsilyl enol ethers

Treatment of triisopropylsilyl (TIPS) enol ethers with PhIO/TMSN3/at -18 to -15°C rapidly (5 min) gave β-azido TIPS enol ethers in high yields, with only traces of the α-azido adduct. The reaction is very sensitive to temperature changes, with

New trialkylsilyl enol ether chemistry. Direct β-azido functionalization of triisopropylsilyl enol ethers

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