137897-61-1

Basic information

• Product Name: Benzenesulfonamide, 4-methyl-N-[2-[[tris(1-methylethyl)silyl]oxy]-2-cyclohexen-1-yl]-
• CAS NO: 137897-61-1
• Molecular Formula: C22H37NO3SSi
• Molecular Weight: 423.692
• Mol File: 137897-61-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, 4-methyl-N-[2-[[tris(1-methylethyl)silyl]oxy]-2-cyclohexen-1-yl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, 4-methyl-N-[2-[[tris(1-methylethyl)silyl]oxy]-2-cyclohexen-1-yl]-(137897-61-1)
• EPA Substance Registry System: Benzenesulfonamide, 4-methyl-N-[2-[[tris(1-methylethyl)silyl]oxy]-2-cyclohexen-1-yl]-(137897-61-1)

Safety Data

• Hazardous Substances Data: 137897-61-1(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 127-65-1 chloroamine-T 
• 80522-46-9 1-triisopropylsiloxy-1-cyclohexene 
• 60123-29-7 N,N'-di(p-tolylsulfonyl)selenium diimide 

Relevant articles and documents

New Trialkylsilyl Enol Ether Chemistry: α-N-Tosylamination of Triisopropylsilyl Enol Ethers

Triisopropylsilyl enol ethers react with (TsN)2Se to give α-N-tosylamino derivatives in modest to good yields.In the absence of 1,3-diaxial interactions the N-tosylamino group prefers an axial conformation.The axial N-tosylamino derivatives can be readily transformed into the azabicyclononane skeleton, the core structure of a number of alkaloids.