137919-07-4

Basic information

• Product Name: Benzoic acid, 4-methoxy-, 2-cyclopenten-1-yl ester
• CAS NO: 137919-07-4
• Molecular Formula: C13H14O3
• Molecular Weight: 218.252
• Mol File: 137919-07-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-methoxy-, 2-cyclopenten-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-methoxy-, 2-cyclopenten-1-yl ester(137919-07-4)
• EPA Substance Registry System: Benzoic acid, 4-methoxy-, 2-cyclopenten-1-yl ester(137919-07-4)

Safety Data

• Hazardous Substances Data: 137919-07-4(Hazardous Substances Data)

Upstream product

• 3212-60-0 cyclopent-2-enol 
• 100-07-2 4-methoxy-benzoyl chloride 
• 100-09-4 4-methoxybenzoic acid 
• 142-29-0 cyclopentene 
• 287-92-3 Cyclopentane 

Relevant articles and documents

Copper porphyrin as efficient catalysts for esterification of allyl sp3 C–H bond with carboxylic acid

We described that copper 5,10,15,20-tetrakis (ethoxycarbonyl)porphyrin (TECP) catalyzed oxidative cross dehydrogenative coupling of allyl sp3 C–H bond with acid for the synthesis of allyl esters in a homogeneous system. This reaction proceeded

Allylic oxidation of alkenes catalyzed by a copper-aluminum mixed oxide

A strategy for the allylic oxidation of cyclic alkenes with a copper-aluminum mixed oxide as catalyst is presented. The reaction involves the treatment of an alkene with a carboxylic acid employing tert-butyl hydroperoxide as the oxidant. In all cases, the corresponding allylic esters are obtained. When l-proline is employed, the allylic alcohol or ketone is obtained. The oxidation of cyclohexene and valencene has been optimized by design of experiments (DoE) statistical methodology.