1379592-24-1Relevant articles and documents
DBU-Mediated cleavage of aryl- and heteroaryl disulfides
Nyoni, Dubekile,Lobb, Kevin A.,Kaye, Perry T.,Caira, Mino R.
experimental part, p. 245 - 252 (2012/05/31)
The capacity of the nitrogen nucleophile, 1,8-diazabicyclo[5.4.0]undec-7- ene (DBU) to reduce aryl- and heteroaryl disulfides to the corresponding mercaptans is demonstrated. While dicarboxylated disulfide analogues afford the mono-DBU disulfide salts, as confirmed by X-ray crystallography, the corresponding methyl esters are cleaved normally. ARKAT-USA, Inc.