1379659-98-9

Basic information

• Product Name: C₃₀H₃₂O₆Si
• CAS NO: 1379659-98-9
• Molecular Weight: 516.666
• Mol File: 1379659-98-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₀H₃₂O₆Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₀H₃₂O₆Si(1379659-98-9)
• EPA Substance Registry System: C₃₀H₃₂O₆Si(1379659-98-9)

Safety Data

• Hazardous Substances Data: 1379659-98-9(Hazardous Substances Data)

Upstream product

• 1379659-82-1 [(3aS,7aR)-2,2-dimethyl-7aH-benzo[1,3]dioxol-3a-yl]methyl benzoate 
• 1379659-83-2 C₁₇H₁₈O₆ 
• 1379659-84-3 C₁₇H₂₀O₆ 
• 1379659-95-6 C₃₃H₃₈O₆Si 
• 1379659-97-8 C₃₃H₃₆O₆Si 
• 32359-20-9 (1S,2R)-1,2-dihydroxycyclohexa-3,5-diene-1-carboxylic acid 
• 172877-76-8 ((3aR,7aR)-2,2-dimethyl-3a,7a-dihydrobenzo[d][1,3]dioxol-3a-yl)methanol 
• 172877-74-6 (-)-(3aS,7aR)-2,2-dimethyl-3a,7a-dihydrobenzo[d][1,3]dioxole-3a-carboxylic acid 
• 172877-75-7 (3aS,7aR)-methyl 2,2-dimethyl-3a,7a-dihydrobenzo[d][1,3]dioxole-3a-carboxylate 

Relevant articles and documents

Photooxygenation of a microbial arene oxidation product and regioselective Kornblum-DeLamare rearrangement: Total synthesis of zeylenols and zeylenones

We report the enantioselective total syntheses of zeylenol (+)-1, as well as its congeners (-)-7 and 16, and of 3-O-debenzoylzeylenone 28. To this end, a new variant of the Kornblum-DeLaMare rearrangement, which utilises neighbouring-group participation to impart regioselectivity, has been developed. The approach employs photooxygenation of building blocks derived from a microbial arene oxidation product. New light on a Korny rearrangement: Biooxidation of benzoic acid with R. eutrophus B9 gives a dearomatised diene diol acid that allows concise access to the zeylenol and zeylenone family of polyoxygenated cyclohexene natural products. The synthesis employs diene photooxygenation and a new regioselective variant of the Kornblum-DeLaMare endoperoxide fragmentation has been developed (see scheme).