1379664-49-9Relevant articles and documents
On the Regioselectivity of the Nickel-Catalyzed Insertion of Alkynes into the Carbon-Carbon Bond of Oxetan-3-one
Barday, Manuel,Janot, Christopher,Clare, Daniel,Carr-Knox, Caitlin,Higginson, Bradley,Ho, Kelvin Y. T.,A?ssa, Christophe
, p. 3582 - 3589 (2017/08/16)
The study of the regioselectivity of insertion of unsymmetrical alkynes into the carbon-carbon bond of oxetan-3-one in the presence of a nickel catalyst has revealed a strong directing effect of a 2-thienyl substituent. This effect is larger than those of 2-vinylbenzene, trimethylsilyl, aryl, or 3-thienyl groups.