138089-76-6Relevant articles and documents
Total Synthesis of rac-Sesquiterpenoid AE 1
Schinzer, Dieter,Fessner, Klaus,Ruppelt, Martin
, p. 139 - 144 (2007/10/02)
rac-Sesquiterpenoid AE 1 (rac-1) can be obtained in an 11-step sequence starting from 5-methylresorcinol (2).The key compound 9 is synthesized by the use of a diastereoselective dienone cyclization with the allylic silane 8.Subsequent transformation of 9 leads to rac-1. Key Words: Sesquiterpenoid AE 1 / Dienone cyclization / Allylsilane