138103-22-7Relevant articles and documents
Fluxional Behaviour of Isocyanide Derivatives of Dodecacarbonyltetrairidium
Orlandi, Alessandra,Ros, Renzo,Roulet, Raymond
, p. 1464 - 1470 (2007/10/02)
The fluxional behaviour of (1) and (Ar=4-methoxyphenyl, 4-tolyl, phenyl, 4-chlorophenyl, 4-nitrophenyl; 2-5) has been investigated by 2D and variable-temperature 13C-NMR.These techniques give new evidence of the processes responsible for CO exchange, namely two successive merry-go-rounds causing Cotton-like scrambling and a CO rotation about one metal center.