138145-58-1

Basic information

• Product Name: Pentanedinitrile, 3-(benzoyloxy)-
• CAS NO: 138145-58-1
• Molecular Formula: C12H10N2O2
• Molecular Weight: 214.224
• Mol File: 138145-58-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pentanedinitrile, 3-(benzoyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pentanedinitrile, 3-(benzoyloxy)-(138145-58-1)
• EPA Substance Registry System: Pentanedinitrile, 3-(benzoyloxy)-(138145-58-1)

Safety Data

• Hazardous Substances Data: 138145-58-1(Hazardous Substances Data)

Upstream product

• 13880-89-2 3-hydroxyglutaronitrile 
• 98-88-4 benzoyl chloride 

Downstream Products

• 147963-59-5 Benzoic acid (S)-2-cyano-1-[((R)-1-naphthalen-1-yl-ethylcarbamoyl)-methyl]-ethyl ester 
• 147963-59-5 Benzoic acid (S)-2-cyano-1-[((S)-1-naphthalen-1-yl-ethylcarbamoyl)-methyl]-ethyl ester 
• 147028-56-6 (S)-(+)-methyl-(3-O--4-cyano)-butanoate 
• 138145-61-6 (S)-(+)-3-O-(benzoyl)-4-cyanobutanoic acid 
• 65-85-0 benzoic acid 

Relevant articles and documents

Stereoselective Hydrolysis of Nitriles and Amides Under Mild Conditions Using a Whole Cell Catalyst

An immobilised whole cell Rhodococcus sp. (SP 361) has been shown to be an effective catalyst for the stereoselective hydrolysis of both racemic and prochiral nitrile containing compounds. 2-Alkyl-arylacetonitriles 6a-8a were hydrolysed to (S)-acids and (R)-amides whereas the closely related substrate 9a gave the (R)-acid.A series of prochiral dinitriles 10a-13a were hydrolysed to the corresponding (S)-acids with e.e.'s 22-84percent.Models to account for the stereoselectivity of the enzymic hydrolyses have been proposed.