13827-44-6Relevant articles and documents
An efficient catalytic and solvent-free method for the synthesis of mono-organofunctionalized 1,1,3,3-tetramethyldisiloxane derivatives
Januszewski, Rafa?,Kownacki, Ireneusz,Maciejewski, Hieronim,Marciniec, Bogdan
, p. 263 - 268 (2017)
Selective mono-functionalization of 1,1,3,3-tetramethyldisiloxane (TMDSO) with olefins via hydrosilylation reaction is reported. On the basis of a study of platinum- and rhodium complexes in the reactions between TMDSO and selected olefins containing C=C bond, it was possible to choose the most efficient catalyst whose application in the solvent-free system led to selective mono-functionalization of the disiloxane reagent and simultaneous formation of only β-regioisomeric products, bearing in their structure functional groups of unique reactivity or physicochemical properties.