1383003-83-5

Basic information

• Product Name: (R)-2-((benzyloxy)methyl)-4-butyl-2,5-dimethylcyclopent-4-ene-1,3-dione
• Synonyms: (R)-2-((benzyloxy)methyl)-4-butyl-2,5-dimethylcyclopent-4-ene-1,3-dione
• CAS NO: 1383003-83-5
• Molecular Weight: 300.398
• Mol File: 1383003-83-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-2-((benzyloxy)methyl)-4-butyl-2,5-dimethylcyclopent-4-ene-1,3-dione(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-((benzyloxy)methyl)-4-butyl-2,5-dimethylcyclopent-4-ene-1,3-dione(1383003-83-5)
• EPA Substance Registry System: (R)-2-((benzyloxy)methyl)-4-butyl-2,5-dimethylcyclopent-4-ene-1,3-dione(1383003-83-5)

Safety Data

• Hazardous Substances Data: 1383003-83-5(Hazardous Substances Data)

Upstream product

• 627-05-4 1-nitrobutane 
• 1383003-29-9 2-((benzyloxy)methyl)-2-methylcyclopent-4-ene-1,3-dione 
• 856177-89-4 2-((benzyloxy)methyl)-2-methylcyclopentane-1,3-dione 

Relevant articles and documents

Ag(I)-Catalyzed Kinetic Resolution of Cyclopentene-1,3-diones

An efficient kinetic resolution of readily available racemic cyclopentene-1,3-diones has been developed via a Ag(I)-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides. This methodology shows good functional-group tolerance, delivering an array of synthetically valuable cyclopentene-1,3-diones with excellent stereoselectivity and generally high resolution efficiency (s = 48-226) accompanied by the biologically important fused pyrrolidine derivatives. Notably, this strategy allows facile access to the key intermediates for the synthesis of (+)-madindolines A and B.