138397-66-7

Basic information

• Product Name: {bis(2-diphenylphosphinoethyl)phenylphosphine-κ(3)P,P',P''}bis(phenylthio-κS)cobalt(II)
• CAS NO: 138397-66-7
• Molecular Weight: 811.894
• Mol File: 138397-66-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {bis(2-diphenylphosphinoethyl)phenylphosphine-κ(3)P,P',P''}bis(phenylthio-κS)cobalt(II)(CAS DataBase Reference)
• NIST Chemistry Reference: {bis(2-diphenylphosphinoethyl)phenylphosphine-κ(3)P,P',P''}bis(phenylthio-κS)cobalt(II)(138397-66-7)
• EPA Substance Registry System: {bis(2-diphenylphosphinoethyl)phenylphosphine-κ(3)P,P',P''}bis(phenylthio-κS)cobalt(II)(138397-66-7)

Safety Data

• Hazardous Substances Data: 138397-66-7(Hazardous Substances Data)

Upstream product

• 930-69-8 sodium thiophenolate 
• 23582-02-7 bis(2-diphenylphosphinoethyl)phenylphosphine 

Relevant articles and documents

Stereochemistry of Mixed Thiolate and Ditertiary Phosphine Cobalt(II) Complexes. Crystal Structures of (SPh)2> and (SPh2)2>

The complexes and were prepared in good yields by treating Co(dppp)Cl2 with NaSPh and elemental selenium in dimethylformamide and by treating CoCl2*6H2O and bdpp in acetonitrile with NaSPh, respectively.The complex crystallizes in the triclinic space group P, with a = 9.665(2), b = 10.075(1), c = 18.288(2) Angstroem, α = 102.41(1), β = 93.89(1), γ = 92.40(1) deg and Z = 2, whereas the complex is monoclinic, space group Cc, with a = 16.374(2), b = 26.033(3), c = 10.873(5) Angstroem, β = 117.49(2) deg and Z = 4.