138433-61-1Relevant articles and documents
Synthesis of (+)-obtusenyne
Mak, S.Y. Frankie,Curtis, Neil R.,Payne, Andrew N.,Congreve, Miles S.,Wildsmith, Andrew J.,Francis, Craig L.,Davies, John E.,Pascu, Sofia I.,Burton, Jonathan W.,Holmes, Andrew B.
supporting information; experimental part, p. 2867 - 2885 (2009/06/17)
An enantioselective synthesis of the halogenated medium-ring ether natural product (+)-obtusenyne is reported which uses the ring expansion of a seven-membered ketene acetal by means of a Claisen rearrangement to construct the core nine-membered oxygen he
Synthetic studies on palytoxin. Stereocontrolled, practical synthesis of the C.101-C.115 segment
Ko,Klein,Pfaff,Kishi
, p. 4415 - 4418 (2007/10/02)
A stereocontrolled and practical synthetic route to the acetal 2a, a degradation product of palytoxin, in optically active form is described.