1384870-55-6

Basic information

• Product Name: 3-((tert-butyldiphenylsilyloxy)methyl)-4-(2-(2-methyl-1,3-dioxolan-2-yl)ethyl)-5-methylene-4-(triethylsilyloxy)cyclopent-2-enone
• Synonyms: 3-((tert-butyldiphenylsilyloxy)methyl)-4-(2-(2-methyl-1,3-dioxolan-2-yl)ethyl)-5-methylene-4-(triethylsilyloxy)cyclopent-2-enone
• CAS NO: 1384870-55-6
• Molecular Weight: 606.95
• Mol File: 1384870-55-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-((tert-butyldiphenylsilyloxy)methyl)-4-(2-(2-methyl-1,3-dioxolan-2-yl)ethyl)-5-methylene-4-(triethylsilyloxy)cyclopent-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-((tert-butyldiphenylsilyloxy)methyl)-4-(2-(2-methyl-1,3-dioxolan-2-yl)ethyl)-5-methylene-4-(triethylsilyloxy)cyclopent-2-enone(1384870-55-6)
• EPA Substance Registry System: 3-((tert-butyldiphenylsilyloxy)methyl)-4-(2-(2-methyl-1,3-dioxolan-2-yl)ethyl)-5-methylene-4-(triethylsilyloxy)cyclopent-2-enone(1384870-55-6)

Safety Data

• Hazardous Substances Data: 1384870-55-6(Hazardous Substances Data)

Upstream product

• 76420-07-0 4-hydroxy-2-(hydroxymethyl)cyclopent-2-en-1-one 
• 1384870-79-4 3-((tert-butyldiphenylsilyloxy)methyl)-4-(2-(2-methyl-1,3-dioxolan-2-yl)ethyl)-4-(triethylsilyloxy)cyclopent-2-enone 
• 33797-51-2 eschenmoser's salt 
• 1384870-78-3 3-((tert-butyldiphenylsilyloxy)methyl)-4-hydroxy-4-(2-(2-methyl-1,3-dioxolan-2-yl)ethyl)cyclopent-2-enone 
• 1384870-71-6 C₂₂H₂₆O₃Si 
• 53750-51-9 2-methyl-2-(2-iodoethyl)-1,3-dioxolane 
• 76374-24-8 2,5-dihydro-3-hydroxymethyl-2,5-dimethoxy-2-methylfuran 
• 5554-99-4 (2-methylfuran-3-yl)methanol 
• 28921-35-9 2-methyl-3-ethoxycarbonyl-furan 

Relevant articles and documents

Formal synthesis of merrilactone a using a domino cyanide 1,4-addition-aldol cyclization

A formal synthesis of merrilactone A has been completed using a domino 1,4-addition-aldol process as the key step. Both iodo- and cyano-1,4-addition- aldol cyclizations were productive in forming the highly hindered C1-C9 bond linking vic-quaternary and tertiary stereocenters. The latter method was used to complete a formal total synthesis of the natural product.