1384980-49-7

Basic information

• Product Name: N-[2,2-dimethyl-3-(4-bromophenyl)propanoyl]-S-methyl-S-2-pyridylsulfoximine
• Synonyms: N-[2,2-dimethyl-3-(4-bromophenyl)propanoyl]-S-methyl-S-2-pyridylsulfoximine
• CAS NO: 1384980-49-7
• Molecular Weight: 395.32
• Mol File: 1384980-49-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-[2,2-dimethyl-3-(4-bromophenyl)propanoyl]-S-methyl-S-2-pyridylsulfoximine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[2,2-dimethyl-3-(4-bromophenyl)propanoyl]-S-methyl-S-2-pyridylsulfoximine(1384980-49-7)
• EPA Substance Registry System: N-[2,2-dimethyl-3-(4-bromophenyl)propanoyl]-S-methyl-S-2-pyridylsulfoximine(1384980-49-7)

Safety Data

• Hazardous Substances Data: 1384980-49-7(Hazardous Substances Data)

Upstream product

• 76456-06-9 imino(methyl)(pyridin-2-yl)-λ⁶-sulfanone 
• 186498-30-6 1-bromo-4-(2-carboxy-2-methylpropyl)benzene 
• 1384980-70-4 N-[3-acetoxy-2-benzyl-2-methylpropanoyl]-S-methyl-S-2-pyridylsulfoximine 
• 1384980-51-1 N-[2,2-dimethyl-3-phenylpropanoyl]-S-methyl-S-2-pyridylsulfoximine 
• 951787-81-8 N-(4-nitrobenzenesulfonyl) methyl (2-pyridinyl) sulfoximine 
• 21948-75-4 2-methylsulfinylpyridine 
• 18438-38-5 2-methylsulfanyl-pyridine 
• 2637-34-5 2-Sulfanylpyridine 

Downstream Products

• 1384980-68-0 N-[3-acetoxy-2-(4-bromobenzyl)-2-methylpropanoyl]-S-methyl-S-2-pyridylsulfoximine 
• 1384980-79-3 N-[3-acetoxy-2-(acetoxymethyl)-2-(4-bromobenzyl)propanoyl]-S-methyl-S-2-pyridylsulfoximine 

Relevant articles and documents

Sulfoximine assisted Pd(II)-catalyzed bromination and chlorination of primary β-C(sp3)-H bond

S-Methyl-S-2-pyridyl-sulfoximine (MPyS) directed bromination and chlorination of the 1°-β-C(sp3)-H bond of MPyS-N-amides is realized under the influence of N-Br/Cl-phthalimides and a Pd(II)-catalyst. The sequential halogenation and acetoxylation of α-dimethyl MPyS-N-amides constructs highly functionalized α-trisubstituted aliphatic acid derivatives. The MPyS directing group is cleaved from the halogenated products and recovered. (Chemical Equation Presented).