138505-25-6Relevant articles and documents
Tris(perfluoroalkyl)silyl entities as unexpectedly potent tags for the noncovalent immobilization of catalysts by fluorous-fluorous interactions: Application to the synthesis of several perfluoro-tagged ligands
Andrushko, Vasyl,Schwinn, Dominik,Tzschucke, Carl Christoph,Michalek, Florian,Horn, Joachim,Moessner, Christian,Bannwarth, Willi
, p. 936 - 949 (2005)
Unexpectedly high retention times were obtained in HPLC investigations for compounds equipped with (C8F17CH2CH 2)3Si tags on C8F17-modified silica gel (Fig. 4). Hence, these tags have a high potential for the noncovalent immobilization of catalysts to be applied in organic solvents, allowing for an easy separation and reuse of the catalyst by filtration and reapplication. The tris(perfluoroalkyl)silyl tag could be incorporated in a straightforward manner into ligands as demonstrated by the synthesis of several prominent classes of ligands (Schemes 4-6).
S1P1 AGONIST AND APPLICATION THEREOF
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Paragraph 0375; 0379-0381, (2021/10/02)
The present invention relates to a class of tricyclic compounds and an application thereof as a sphingosine 1-phosphate type 1 (S1P1) receptor agonist. The invention specifically relates to a compound represented by formula (II), and a tautomer and pharmaceutically acceptable salt of same.
Phosphinate ruthenium complexes
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Page/Page column 44; 45, (2015/09/23)
Provided herein are ruthenium complexes of Formula I, and processes of preparation thereof. Also provided are methods of their use as a metathesis catalyst.