13863-59-7Relevant articles and documents
Reaction of limonene with F2: Rate coefficient and products
Bedjanian, Yuri,Romanias, Manolis N.,Morin, Julien
, p. 10233 - 10239 (2015/02/19)
The kinetics of the reaction of limonene (C10H16) with F2 has been studied using a low pressure (P = 1 Torr) and a high pressure turbulent (P = 100 Torr) flow reactor coupled with an electron impact ionization and chemical ionization mass spectrometers, respectively: F2 + Limonene → products (1). The rate constant of the title reaction was determined under pseudo-first-order conditions by monitoring either limonene or F2 decay in excess of F2 or C10H16, respectively. The reaction rate constant, k1 = (1.15 ± 0.25) × 10-12 exp(160 ± 70)/T) was determined over the temperature range 278-360 K, independent of pressure between 1 (He) and 100 (N2) Torr. F atom and HF were found to be formed in reaction 1, with the yields of 0.60 ± 0.13 and 0.39 ± 0.09, respectively, independent of temperature in the range 296-355 K. (Graph Presented).
