13865-50-4 Usage
Description
Methoxymethyl phenyl sulfide is an organic compound that is known for its chemical reactivity and potential applications in various industries. It is characterized by its ability to undergo chemical transformations, such as the Meisenheimer rearrangement and oxidation reactions, which make it a versatile compound for further synthesis and development.
Uses
Used in Chemical Synthesis:
Methoxymethyl phenyl sulfide is used as a precursor in the chemical synthesis of methoxymethyl phenyl sulfoxide. METHOXYMETHYL PHENYL SULFIDE serves as an intermediate in the production of various organic compounds, contributing to the development of new materials and chemicals.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, methoxymethyl phenyl sulfide is used as a key component in the synthesis of methoxymethyl phenyl sulfoxide, which can be further transformed into methoxymethyl benzenesulfenate through the Meisenheimer rearrangement. This rearrangement is a significant chemical reaction in the synthesis of various pharmaceutical compounds, making methoxymethyl phenyl sulfide an essential building block in drug development.
Used in Solvent-Free Oxidation Processes:
Methoxymethyl phenyl sulfide is also used in solvent-free permanganate oxidation processes to yield methoxymethyl phenyl sulfone. This oxidation reaction is important in the production of sulfone derivatives, which have a wide range of applications in the chemical and pharmaceutical industries, including the synthesis of dyes, agrochemicals, and pharmaceuticals.
Synthesis Reference(s)
The Journal of Organic Chemistry, 51, p. 879, 1986 DOI: 10.1021/jo00356a025
Check Digit Verification of cas no
The CAS Registry Mumber 13865-50-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,8,6 and 5 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 13865-50:
(7*1)+(6*3)+(5*8)+(4*6)+(3*5)+(2*5)+(1*0)=114
114 % 10 = 4
So 13865-50-4 is a valid CAS Registry Number.
InChI:InChI=1/C8H10OS/c1-9-7-10-8-5-3-2-4-6-8/h2-6H,7H2,1H3
13865-50-4Relevant articles and documents
Electrochemical Properties and Reactions of Sulfur-Containing Organoboron Compounds
Tanigawa, Masahiro,Kuriyama, Yu,Inagi, Shinsuke,Fuchigami, Toshio
, p. 314 - 318 (2016)
Electrochemical analyses of 4,4,5,5-tetramethyl-2-phenylsulfanylmethyl-[1,3,2]dioxaborolane and tetra-n-butylammonium phenylthiomethyltrifluoroborate were comparatively studied by cyclic voltammetry measurements and we found for the first time the β-effect of organoborate, which was indicated by experimental and theoretical aspects. The organoborate was found to have a much lower oxidation potential compared to the organoborane. Anodic substitution reaction of organoboronate ester and organoborate was successfully carried out in the presence of nucleophiles to afford the selectively substituted products in good yields.
Synthesis of dithioacetals and oxathioacetals with chiral auxiliaries
Zaidi, Javid H.,Naeem, Fazal,Khan, Khalid M.,Iqbal, Rasfaid,Zia-Ullah
, p. 2641 - 2653 (2007/10/03)
One-pot synthesis of dithioacetals as well as an efficient method for oxathioacetal is reported. Additionally, some chiral auxiliaries were used to synthesize enantiomerically pure dithioacetals and oxathioacetals.
Spectral and Thermodynamic Characteristics of Complexes of Seleno- and Thioacetals with Iodine
Kazymova,Nedugov,Pavlova,Chmutova
, p. 63 - 66 (2007/10/03)
Seleno- and thioacetal complexes of iodine were studied spectrophotometrically. The spectral and thermodynamic parameters of the complexes are compared with the special features of the electronic and steric structure of the donor molecules and with the characteristics of tetracyanoethylene complexes of the same compounds.
