138815-21-1

Basic information

• Product Name: C₄H₅⁽²⁾H
• Synonyms: C₄H₅⁽²⁾H
• CAS NO: 138815-21-1
• Molecular Weight: 55.0837
• Mol File: 138815-21-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₄H₅⁽²⁾H(CAS DataBase Reference)
• NIST Chemistry Reference: C₄H₅⁽²⁾H(138815-21-1)
• EPA Substance Registry System: C₄H₅⁽²⁾H(138815-21-1)

Safety Data

• Hazardous Substances Data: 138815-21-1(Hazardous Substances Data)

Upstream product

• 71-55-6 1,1,1-trichloroethane 

Relevant articles and documents

Metal ions do not play a direct role in the formation of carbon-carbon triple bonds during reduction of trihaloalkyls by CrII or V II

Carbyne radicals: Reactions of trihaloalkyl compounds with Cr2+ or V2+ in aqueous solutions yield alkynes and other products. Stepwise halogen abstractions from the trihaloalkyls form alkyl carbyne triradicals in solution. These radicals undergo coupling reactions, producing triply bonded alkyne molecules (see scheme). This process is not metal-assisted and does not occur in the coordination sphere of the metal ions.