138815-29-9

Basic information

• Product Name: N-Benzoyl-2-phenyl-4,5-dimethyl-1,2,3-triazol-1-imine
• Synonyms: N-Benzoyl-2-phenyl-4,5-dimethyl-1,2,3-triazol-1-imine
• CAS NO: 138815-29-9
• Molecular Weight: 292.34
• Mol File: 138815-29-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Benzoyl-2-phenyl-4,5-dimethyl-1,2,3-triazol-1-imine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Benzoyl-2-phenyl-4,5-dimethyl-1,2,3-triazol-1-imine(138815-29-9)
• EPA Substance Registry System: N-Benzoyl-2-phenyl-4,5-dimethyl-1,2,3-triazol-1-imine(138815-29-9)

Safety Data

• Hazardous Substances Data: 138815-29-9(Hazardous Substances Data)

Upstream product

• 100-63-0 phenylhydrazine 
• 55590-53-9 biacetyl monobenzoyl hydrazone 
• 31400-24-5 Biacetyl Benzoylhydrazone Phenylhydrazone 

Downstream Products

• 58737-90-9 4,5-Dimethyl-2-phenyl-2H-1,2,3-triazole 
• 31280-33-8 N-(benzoyl)-S,S-dimethylsulfoximine 
• 1575-94-6 N,N'-methylenebisbenzamide 
• 55-21-0 benzamide 

Relevant articles and documents

1,2,3-Triazol-1-imines. 1. The Synthesis and Lead Tetraacetate Oxidation of Biacetyl Benzoylhydrazone Arylhydrazones to the Novel 2-Aryl-N-benzoyl-4,5-dimethyl-1,2,3-triazol-1-imines

The synthesis and the Pb(OAc)4 oxidation of the mixed bishydrazones of biacetyl 7 was studied.The formation of the novel N-benzoyl-1,2,3-triazol-1-imines 9 from the oxidation of 7 provided support to the proposed in the past mechanism for the oxidation of bis-aroylhydrazones of α-dicarbonyl compounds 4.Thermolysis and photolysis of 9a in DMSO was carried out.The results suggested that benzoylnitrene was formed in the photochemical reaction, and therefore compounds such as 9 could serve as non-azide aroyl nitrene precursors.For 9a the results of the X-ray analysis were correlated with charge densities and bond orders gleaned by the MNDO method.Product 9d was alternatively synthesized by the addition of photochemically generated bezoylnitrene to the 1,2,3-triazole 21.