13886-09-4Relevant articles and documents
Systematic study on the catalytic synthesis of unsaturated 2-ketocarboxamides: Palladium-catalyzed double carbonylation of 1-iodocyclohexene
Carrilho, Rui M.B.,Pereira, Mariette M.,Takács, Attila,Kollár, László
experimental part, p. 204 - 207 (2012/01/05)
1-Iodocyclohexene, a benchmark substrate, has been double carbonylated in the presence of palladium-phosphite precatalysts. Triarylphosphites with OR substituents, able to act both as P-monodentate and hemilabile P,O-heterobidentate ligands were used in t